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Designing the solid–electrolyte interphase (SEI) is critical for stable, fast-charging, low-temperature Li-ion batteries. Fostering a “fluorinated interphase,” SEI enriched with LiF, has become a popular design strategy. Although LiF possesses low Li-ion conductivity, many studies have reported favorable battery performance with fluorinated SEIs. Such a contradiction suggests that optimizing SEI must extend beyond chemical composition design to consider spatial distributions of different chemical species. In this work, we demonstrate that the impact of a fluorinated SEI on battery performance should be evaluated on a case-by-case basis. Sufficiently passivating the anode surface without impeding Li-ion transport is key. We reveal that a fluorinated SEI containing excessive and dense LiF severely impedes Li-ion transport. In contrast, a fluorinated SEI with well-dispersed LiF (i.e., small LiF aggregates well mixed with other SEI components) is advantageous, presumably due to the enhanced Li-ion transport across heterointerfaces between LiF and other SEI components. An electrolyte, 1 M LiPF₆in 2-methyl tetrahydrofuran (2MeTHF), yields a fluorinated SEI with dispersed LiF. This electrolyte allows anodes of graphite, μSi/graphite composite, and pure Si to all deliver a stable Coulombic efficiency of 99.9% and excellent rate capability at low temperatures. Pouch cells containing layered cathodes also demonstrate impressive cycling stability over 1,000 cycles and exceptional rate capability down to −20 °C. Through experiments and theoretical modeling, we have identified a balanced SEI-based approach that achieves stable, fast-charging, low-temperature Li-ion batteries. 

Abstract Temporal changes in seismic velocity estimated from ambient seismic noise can be utilized to infer subsurface properties at volcanic systems. In this study, we process 7 years of continuous seismic noise at Axial Seamount and use cross‐correlation functions to calculate the relative seismic velocity changes (dv/v) beneath the caldera. We find a long‐term trend of decreasing velocity during rapid inflation, followed by slight increase in velocities as background seismicity increases and inflation rate decreases. Furthermore, we observe small short‐term increases indv/vwhich coincide with short‐term deflation events. Our observations of changes indv/vand their correlation with other geophysical data provide insights into how the top ∼1 km of the crust at Axial Seamount changes in response to subsurface magma movement and capture the transition from a period of rapid reinflation to a period where the caldera wall faults become critically stressed and must rupture to accommodate further inflation. 

Cosmic Explorer is a next-generation ground-based gravitational-wave observatory that is being designed in the 2020s and is envisioned to begin operations in the 2030s together with the Einstein Telescope in Europe. The Cosmic Explorer concept currently consists of two widely separated L-shaped observatories in the United States, one with 40 km-long arms and the other with 20 km-long arms. This order of magnitude increase in scale with respect to the LIGO-Virgo-KAGRA observatories will, together with technological improvements, deliver an order of magnitude greater astronomical reach, allowing access to gravitational waves from remnants of the first stars and opening a wide discovery aperture to the novel and unknown. In addition to pushing the reach of gravitational-wave astronomy, Cosmic Explorer endeavors to approach the lifecycle of large scientific facilities in a way that prioritizes mutually beneficial relationships with local and Indigenous communities. This article describes the (scientific, cost and access, and social) criteria that will be used to identify and evaluate locations that could potentially host the Cosmic Explorer observatories. 

Abstract Shear attenuation provides insights into the physical and chemical state of the upper mantle. Yet, observations of attenuation are infrequent in the oceans, despite recent proliferation of arrays of ocean‐bottom seismometers (OBSs). Studies of attenuation in marine environments must overcome unique challenges associated with strong oceanographic noise at the seafloor and data loss during OBS recovery in addition to untangling the competing influences of elastic focusing, local site amplification, and anelastic attenuation on surface‐wave amplitudes. We apply Helmholtz tomography to OBS data to simultaneously resolve array‐averaged Rayleigh wave attenuation and maps of site amplification at periods of 20–150 s. The approach explicitly accounts for elastic focusing and defocusing due to lateral velocity heterogeneity using wavefield curvature. We validate the approach using realistic wavefield simulations at the NoMelt Experiment and Juan de Fuca (JdF) plate, which represent endmember open‐ocean and coastline‐adjacent environments, respectively. Focusing corrections are successfully recovered at both OBS arrays, including at periods <35 s at JdF where coastline effects result in strong multipathing. When applied to real data, our observations of Rayleigh wave attenuation at NoMelt and JdF revise previous estimates. At NoMelt, we observe a low attenuation lithospheric layer (> 1,500) overlying a highly attenuating asthenospheric layer (∼ 50 to 70). At JdF, we find a broad peak in attenuation (∼ 50 to 60) centered at a depth of 100–130 km. We also report strong local site amplification at the JdF Ridge (>10% at 31 s period), which can be used to refine models of crust and shallow mantle structure. 

Abstract The Pacific ocean-bottom seismometer (OBS) Research into Convecting Asthenosphere (ORCA) experiment deployed two 30-station seismic arrays between 2018 and 2020—a US contribution to the international PacificArray project. The “Young ORCA” array deployed on ∼40 Ma central Pacific seafloor had a ∼68% data recovery rate, whereas the “Old ORCA” array deployed on ∼120 Ma southwest Pacific seafloor had a ∼80% recovery rate. We detail here the seismic data quality, spectral characteristics, and engineering challenges of this experiment. We provide information to assist users of this dataset, including OBS orientations and tables of daily data quality for all channels. Preliminary analysis illustrates the utility of these data for surface- and body-wave seismic imaging.